Tech. Tip:More Than
You Ever Wanted to Know About Motor Oil
By: Ed
Hackett
Oil
companies provide data on their oils most
often referred to as "typical
inspection data". This is an average
of the actual physical and a few common
chemical properties of their oils. This
information is available to the public
through their distributors or by writing
or calling the company directly. I have
compiled a list of the most popular,
premium oils so that a ready comparison
can be made. If your favorite oil is not
on the list get the data from the
distributor and use what I have as a data
base.
This
article is going to look at six of the
most important properties of a motor oil
readily availiable to the public: viscosity, viscosity
index (VI), flash
point,
pour point, %
sulfated ash, and %
zinc.
Viscosity
Viscosity
is a measure of the
"flowability" of an oil. More
specifically, it is the property of an
oil to develop and maintain a certain
amount of sheering stress dependent on
flow and then to offer continued
resistance to flow. Thicker oils
generally have a higher viscosity, and
thinner oils a lower viscosity. This is
the most important property for an
engine. An oil with too low a viscosity
can shear and loose film strength at high
temperatures. An oil with too high a
viscosity may not pump to the proper
parts at low temperatures and the film
may tear at high rpm.
The
weights given on oils are arbitrary
numbers assigned by the S.A.E. (Society
of Automotive Engineers). These numbers
correspond to "real" viscosity,
as measured by several accepted
techniques. These measurements are taken
at specific temperatures. Oils that fall
into a certain range are designated 5,
10, 20, 30, 40, 50 by the S.A.E. The W
means the oil meets specifications for
viscosity at various low temperatures
depending on weight, and is therefore
suitable for Winter use. 5W is tested at
-25C, 10W at -20C, 15W at -15C, and 20W
at -10C.
Multi-viscosity
Multi
viscosity oils work like this: Polymers
are added to a light base(5W, 10W, 20W),
which prevent the oil from thinning as
much as it warms up. At cold temperatures
the polymers are coiled up and allow the
oil to flow as their low numbers
indicate. As the oil warms up the
polymers begin to unwind into long chains
that prevent the oil from thinning as
much as it normally would. The result is
that at 100 degrees C the oil has thinned
only as much as the higher viscosity
number indicates. Another way of looking
at multi-vis oils is to think of a 20W-50
as a 20 weight oil that will not thin
more than a 50 weight would when hot.
Choosing your oil!
Multi
viscosity oils are one of the great
improvements in oils, but they should be
chosen wisely. Always use a multi grade
with the narrowest span of viscosity that
is appropriate for the temperatures you
are going to encounter. In the winter
base your decision on the lowest
temperature you will encounter, in the
summer, the highest temperature you
expect. The polymers can shear and burn
forming deposits that can cause ring
sticking and other problems. 10W-40 and
5W-30 require a lot of
polymers(synthetics excluded) to achieve
that range. This has caused problems in
diesel engines, but fewer polymers are
better for all engines. The wide
viscosity range oils, in general, are
more prone to viscosity and thermal
breakdown due to the high polymer
content. It is the oil that lubricates,
not the additives. Oils that can do their
job with the fewest additives are the
best.
Very few
manufacturers recommend 10W-40 any more,
and some threaten to void warranties if
it is used. It was not included in this
article for that reason. 20W-50 is the
same 30 point spread, but because it
starts with a heavier base it requires
less viscosity index improvers (polymers)
to do the job. AMSOIL can formulate
their 10W-30 and 15W-40 with no viscosity
index improvers but uses some in the
10W-40 and 5W-30. Other multigrade
synthetics may not use VI improvers
either. The full literature available
from the oil company should include this
information. Follow your manufacturer's
recommendations as to which weights are
appropriate for your vehicle.
Viscosity Index
Viscosity
Index is an empirical number indicating
the rate of change in viscosity of an oil
within a given temperature range. Higher
numbers indicate a low change, lower
numbers indicate a relatively large
change. The higher the number the better.
This is one major property of an oil that
keeps your bearings happy. These numbers
can only be compared within a viscosity
range. It is not an indication of how
well the oil resists thermal breakdown.
Flash Point
Flash
point is the temperature at which an oil
gives off vapors that can be ignited with
a flame held over the oil. The lower the
flash point the greater tendancy for the
oil to suffer vaporization loss at high
temperatures and to burn off on hot
cylinder walls and pistons. The flash
point can be an indicator of the quality
of the base stock used. The higher the
flash point the better. 400 F is the
minimum to prevent possible high
consumption. Flash point is in degrees F.
Pour Point
(Fahrenheit)
Pour point
is 5 degrees F above the point at which a
chilled oil shows no movement at the
surface for 5 seconds when inclined. This
measurement is especially important for
oils used in the winter. A borderline
pumping temperature is given by some
manufacturers. This is the temperature at
which the oil will pump and maintain
adequate oil pressure. This was not given
by a lot of the manufacturers, but seems
to be about 20 degrees F above the pour
point. The lower the pour point the
better. Pour point is in degrees F.
Sulfated Ash
% sulfated
ash is how much solid material is left
when the oil is reacted with sulfuric
acid and burned. This is used to quantify
the amount of metallic antiwear and
detergent additives in the oil. Zinc
dithiophosphate is a common detergent and
antiwear additive that is reflected in
this test.
Zinc
% zinc is
the amount of zinc used as an extreme
pressure, anti- wear additive. The zinc
is only used when there is actual metal
to metal contact in the engine. Hopefully
the oil will do its job and this will
rarely occur, but if it does, the zinc
compounds react with the metal to prevent
scuffing and wear. A level of .11% is
enough to protect an automobile engine
for the extended oil drain interval,
under normal use. Those of you with high
reving, air cooled motorcycles or ATV's
might want to look at the oils with the
higher zinc content. More doesn't give
you better protection, it gives you
longer protection if the rate of metal to
metal contact is abnormally high.
All
Oils are 20W-50W
| Brand |
Visc.
Index |
Flash |
Pour |
%
of Ash |
%
of Zinc |
| Amsoil |
151 |
507 |
-45 |
N/A |
N/A |
| Amsoil
Series 2000 |
155 |
474 |
-47 |
N/A |
N/A |
| Castrol
GTXHavoline Formula |
122 |
440 |
-15 |
.85 |
.12 |
| Chevron
Supreme |
140 |
428 |
-17 |
1.0 |
N/A |
| Exxon
High Performance |
119 |
419 |
-13 |
.70 |
.11 |
| Havoline
Formula 3 |
125 |
465 |
-30 |
1.0 |
N/A |
| Kendall
GT-1 |
129 |
390 |
-25 |
1.0 |
.16 |
| Pennzoil
GT |
120 |
460 |
-10 |
.9 |
N/A |
| Quaker
State Perf. |
121 |
440 |
-20 |
N/A |
N/A |
| Valvoline
Synthetic |
146 |
465 |
-40 |
1.5 |
.12 |
All
Oils are 15W-40W
| Brand |
Viscosity
Index |
Flash |
Pour/deg.(F) |
%
of Ash |
%
of Zinc |
| Amsoil |
165 |
462 |
-49 |
N/A |
N/A |
| Castrol
GTX |
134 |
415 |
-15 |
1.3 |
.14 |
| Exxon
XD3 Extra |
135 |
399 |
-11 |
.95 |
.13 |
| Kendall
GT-1 |
135 |
410 |
-25 |
1.0 |
.16 |
| Quak.
State HDX Plus |
148 |
420 |
-25 |
1.37 |
N/A |
| Valvoline
Turbo |
140 |
420 |
-10 |
.99 |
.13 |
All
Oils are 10W-30W
| Brand |
Visc.
Index |
Flash |
Pour/deg.(F) |
%
of Ash |
%
of Zinc |
| Amsoil |
154 |
520 |
-60 |
N/A |
N/A |
| Castrol
GTX |
140 |
415 |
-33 |
.85 |
.12 |
| Chevron
Supreme |
150 |
419 |
-27 |
.9 |
N/A |
| Exxon
Superflo Supreme |
133 |
400 |
-31 |
.85 |
.13 |
| Havoline
Formula 3 |
139 |
430 |
-30 |
1.0 |
N/A |
| Mobil
1 |
160 |
450 |
-65 |
N/A |
N/A |
| Quaker
State |
140 |
410 |
-30 |
.9 |
N/A |
| Valvoline
Synthetic |
140 |
450 |
-40 |
1.4 |
.12 |
All of the
oils above meet current SG/CD ratings and
all vehicle manufacture's warranty
requirements in the proper viscosity.
The
synthetics offer the only truly
significant differences, due to their
superior high temperature oxidation
resistance, high film strength, very low
tendancy to form deposits, stable
viscosity base, and low temperature flow
characteristics. Synthetics are superior
lubricants compared to traditional
petroleum oils. You will have to decide
if their high cost is justifed in your
application.
Synthetics
can be run two to three times the mileage
of petroleum oils with no problems. They
do not react to combustion and combustion
by-products to the extent that the dead
dinosaur juice does. The longer drain
intervals possible help take the bite out
of the higher cost of the synthetics. If
your ATV or bike is still under warranty
you will have to stick to the recommended
drain intervals. These are set for
petroleum oils and the manufacturers make
no official allowance for the use of
synthetics. Some oil companies, AMSOIL being an example,
offer their own engine warranties. If the
oils are used in compliance with the
company's recommendations (including
extended drain intervals) and a problem
is caused by the engine oil, the company
will pay for the repairs. Check with the
company for specifics of any warranties
offered.
Oil
additives should not be used. The oil
companies have gone to great lengths to
develop an additive package that meets
the vehicle's requirements. Some of these
additives are synergistic, that is the
effect of two additives together is
greater than the effect of each acting
separately. If you add anything to the
oil you may upset this balance and
prevent the oil from performing to
specification.
The
numbers above are not, by any means, all
there is to determining what makes a top
quality oil. The exact base stock used,
the type, quality, and quantity of
additives used are very important. The
given data combined with the
manufacturer's claims, your personal
experience, and the reputation of the oil
among others who use it should help you
make an informed choice.
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